A Manganese(V)–Oxo Tetraamido Macrocyclic Ligand (TAML) Cation Radical Complex: Synthesis, Characterization, and Reactivity Studies

A mononuclear manganese(V)–oxo complex with tetraamido macrocyclic ligand (TAML), [Mn(V)(O)(TAML)](−) (1), is a sluggish oxidant in oxidation reactions. Herein, a mononuclear manganese(V)–oxo TAML cation radical complex, [Mn(V)(O)(TAML(+•))] (2), is reported. It was synthesized by reacting [Mn(III)(...

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Publicado no:Chemistry
Main Authors: Karmalkar, Deepika G., Li, Xiao-Xi, Seo, Mi Sook, Sankaralingam, Muniyandi, Ohta, Takehiro, Sarangi, Ritimukta, Hong, Seungwoo, Nam, Wonwoo
Formato: Artigo
Idioma:Inglês
Publicado em: 2018
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Article
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC6986419/
https://ncbi.nlm.nih.gov/pubmed/30267428
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/chem.201804898
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