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Copper‐Catalyzed Triboration of Terminal Alkynes Using B(2)pin(2): Efficient Synthesis of 1,1,2‐Triborylalkenes
We report herein the catalytic triboration of terminal alkynes with B(2)pin(2) (bis(pinacolato)diboron) using readily available Cu(OAc)(2) and P(n)Bu(3). Various 1,1,2‐triborylalkenes, a class of compounds that have been demonstrated to be potential matrix metalloproteinase (MMP‐2) inhibitors, were...
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| 發表在: | Angew Chem Int Ed Engl |
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| Main Authors: | , , , , |
| 格式: | Artigo |
| 語言: | Inglês |
| 出版: |
John Wiley and Sons Inc.
2019
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| 主題: | |
| 在線閱讀: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6972586/ https://ncbi.nlm.nih.gov/pubmed/31502712 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201908466 |
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