Alpha‐Carbonic Acid Revisited: Carbonic Acid Monomethyl Ester as a Solid and its Conformational Isomerism in the Gas Phase

In this work, earlier studies reporting α‐H(2)CO(3) are revised. The cryo‐technique pioneered by Hage, Hallbrucker, and Mayer (HHM) is adapted to supposedly prepare carbonic acid from KHCO(3). In methanolic solution, methylation of the salt is found, which upon acidification transforms to the monome...

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Publicado en:Chemistry
Main Authors: Köck, Eva‐Maria, Bernard, Jürgen, Podewitz, Maren, Dinu, Dennis F., Huber, Roland G., Liedl, Klaus R., Grothe, Hinrich, Bertel, Erminald, Schlögl, Robert, Loerting, Thomas
Formato: Artigo
Idioma:Inglês
Publicado: John Wiley and Sons Inc. 2019
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Acceso en liña:https://ncbi.nlm.nih.gov/pmc/articles/PMC6972543/
https://ncbi.nlm.nih.gov/pubmed/31593601
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/chem.201904142
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