Alpha‐Carbonic Acid Revisited: Carbonic Acid Monomethyl Ester as a Solid and its Conformational Isomerism in the Gas Phase

In this work, earlier studies reporting α‐H(2)CO(3) are revised. The cryo‐technique pioneered by Hage, Hallbrucker, and Mayer (HHM) is adapted to supposedly prepare carbonic acid from KHCO(3). In methanolic solution, methylation of the salt is found, which upon acidification transforms to the monome...

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Publicat a:Chemistry
Autors principals: Köck, Eva‐Maria, Bernard, Jürgen, Podewitz, Maren, Dinu, Dennis F., Huber, Roland G., Liedl, Klaus R., Grothe, Hinrich, Bertel, Erminald, Schlögl, Robert, Loerting, Thomas
Format: Artigo
Idioma:Inglês
Publicat: John Wiley and Sons Inc. 2019
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Accés en línia:https://ncbi.nlm.nih.gov/pmc/articles/PMC6972543/
https://ncbi.nlm.nih.gov/pubmed/31593601
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/chem.201904142
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