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Low‐Valent Group 14 Phosphinidenide Complexes [({SIDipp}P)(2)M] Exhibit P–M pπ–pπ Interaction (M=Ge, Sn, Pb)

Herein, the synthesis of new low‐valent Group 14 phosphinidenide complexes [({SIDipp}P)(2) m] exhibiting P–M pπ–pπ interactions (SIDipp=1,3‐bis(2,6‐diisopropylphenyl)‐imidazolidin‐2‐ylidene, M=Ge, Sn, Pb), is presented. These compounds were investigated by means of structural, spectroscopic, and qua...

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Détails bibliographiques
Publié dans:Chemistry
Auteurs principaux: Balmer, Markus, Franzke, Yannick J., Weigend, Florian, von Hänisch, Carsten
Format: Artigo
Langue:Inglês
Publié: John Wiley and Sons Inc. 2019
Sujets:
Accès en ligne:https://ncbi.nlm.nih.gov/pmc/articles/PMC6972534/
https://ncbi.nlm.nih.gov/pubmed/31702848
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/chem.201905061
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