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Succinyl-DOTOPA: An effective triradical dopant for low-temperature dynamic nuclear polarization with high solubility in aqueous solvent mixtures at neutral pH

We report the synthesis of the nitroxide-based triradical compound succinyl-DOTOPA and the characterization of its performance as a dopant for dynamic nuclear polarization (DNP) experiments in frozen solutions at low temperatures. Compared with previously described DOTOPA derivatives, succinyl-DOTOP...

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Detalhes bibliográficos
Publicado no:J Magn Reson
Main Authors: Yau, Wai-Ming, Jeon, Jaekyun, Tycko, Robert
Formato: Artigo
Idioma:Inglês
Publicado em: 2019
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC6964257/
https://ncbi.nlm.nih.gov/pubmed/31887554
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1016/j.jmr.2019.106672
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