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Ligand Redox Noninnocence in [Co(III)(TAML)](0/–) Complexes Affects Nitrene Formation
[Image: see text] The redox noninnocence of the TAML scaffold in cobalt-TAML (tetra-amido macrocyclic ligand) complexes has been under debate since 2006. In this work, we demonstrate with a variety of spectroscopic measurements that the TAML backbone in the anionic complex [Co(III)(TAML(red))](–) is...
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| Veröffentlicht in: | J Am Chem Soc |
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| Hauptverfasser: | , , , , , , , , |
| Format: | Artigo |
| Sprache: | Inglês |
| Veröffentlicht: |
American Chemical Society
2019
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| Online Zugang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6956250/ https://ncbi.nlm.nih.gov/pubmed/31846578 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.9b11715 |
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