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Visible-Light-Induced Alkoxyl Radicals Enable α-C(sp(3))-H Bond Allylation

The alkoxyl radical is an essential reactive intermediate in mechanistic studies and organic synthesis with hydrogen atom transfer (HAT) reactivity. However, compared with intramolecular 1,5-HAT or intermolecular HAT of alkoxyl radicals, the intramolecular 1,2-HAT reactivity has been limited to theo...

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Bibliografiska uppgifter
I publikationen:iScience
Huvudupphovsmän: Zhang, Jing, Liu, Dan, Liu, Song, Ge, Yuanyuan, Lan, Yu, Chen, Yiyun
Materialtyp: Artigo
Språk:Inglês
Publicerad: Elsevier 2019
Ämnen:
Länkar:https://ncbi.nlm.nih.gov/pmc/articles/PMC6941871/
https://ncbi.nlm.nih.gov/pubmed/31884167
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1016/j.isci.2019.100755
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