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Visible-Light-Induced Alkoxyl Radicals Enable α-C(sp(3))-H Bond Allylation
The alkoxyl radical is an essential reactive intermediate in mechanistic studies and organic synthesis with hydrogen atom transfer (HAT) reactivity. However, compared with intramolecular 1,5-HAT or intermolecular HAT of alkoxyl radicals, the intramolecular 1,2-HAT reactivity has been limited to theo...
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| Veröffentlicht in: | iScience |
|---|---|
| Hauptverfasser: | , , , , , |
| Format: | Artigo |
| Sprache: | Inglês |
| Veröffentlicht: |
Elsevier
2019
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| Schlagworte: | |
| Online Zugang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6941871/ https://ncbi.nlm.nih.gov/pubmed/31884167 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1016/j.isci.2019.100755 |
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