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Catalytic Enantioselective Pyridine N-Oxidation

The catalytic, enantioselective N-oxidation of substituted pyridines is described. The approach is predicated on a biomolecule-inspired catalytic cycle wherein high levels of asymmetric induction are provided by aspartic acid-containing peptides as the aspartyl side chain shuttles between free acid...

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Détails bibliographiques
Publié dans:J Am Chem Soc
Auteurs principaux: Hsieh, Sheng-Ying, Tang, Yu, Crotti, Simone, Stone, Elizabeth A., Miller, Scott J.
Format: Artigo
Langue:Inglês
Publié: 2019
Sujets:
Accès en ligne:https://ncbi.nlm.nih.gov/pmc/articles/PMC6926419/
https://ncbi.nlm.nih.gov/pubmed/31656070
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.9b10414
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