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Nanoscale Fluid Vortices and Nonlinear Electroosmotic Flow Drive Ion Current Rectification in the Presence of Concentration Gradients

Ion current rectification (ICR) is a transport phenomenon in which an electrolyte conducts unequal currents at equal and opposite voltages. Here, we show that nanoscale fluid vortices and nonlinear electroosmotic flow (EOF) drive ICR in the presence of concentration gradients. The same EOF can yield...

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Pubblicato in:J Phys Chem A
Autori principali: Rabinowitz, Jake, Edwards, Martin A., Whittier, Elizabeth, Jayant, Krishna, Shepard, Kenneth
Natura: Artigo
Lingua:Inglês
Pubblicazione: 2019
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Accesso online:https://ncbi.nlm.nih.gov/pmc/articles/PMC6911310/
https://ncbi.nlm.nih.gov/pubmed/31264868
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.jpca.9b04075
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