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Nanoscale Fluid Vortices and Nonlinear Electroosmotic Flow Drive Ion Current Rectification in the Presence of Concentration Gradients

Ion current rectification (ICR) is a transport phenomenon in which an electrolyte conducts unequal currents at equal and opposite voltages. Here, we show that nanoscale fluid vortices and nonlinear electroosmotic flow (EOF) drive ICR in the presence of concentration gradients. The same EOF can yield...

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Veröffentlicht in:J Phys Chem A
Hauptverfasser: Rabinowitz, Jake, Edwards, Martin A., Whittier, Elizabeth, Jayant, Krishna, Shepard, Kenneth
Format: Artigo
Sprache:Inglês
Veröffentlicht: 2019
Schlagworte:
Online Zugang:https://ncbi.nlm.nih.gov/pmc/articles/PMC6911310/
https://ncbi.nlm.nih.gov/pubmed/31264868
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.jpca.9b04075
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