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Site-selective acylation of natural products with BINOL-derived phosphoric acids
The site-selective acylation of a steroidal natural product 19-hydroxydehydroepiandrosterone catalyzed by 1,1’-Bi(2-napthol)-derived (BINOL) chiral phosphoric acids (CPA’s) is described. Systematic variation and multivariate linear regression analysis reveal that the same steric parameters typically...
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| Publicado no: | ACS Catal |
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| Main Authors: | , , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2019
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6905390/ https://ncbi.nlm.nih.gov/pubmed/31827975 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acscatal.9b03535 |
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