Dissipative Catalysis with a Molecular Machine

We report on catalysis by a fuel‐induced transient state of a synthetic molecular machine. A [2]rotaxane molecular shuttle containing secondary ammonium/amine and thiourea stations is converted between catalytically inactive and active states by pulses of a chemical fuel (trichloroacetic acid), whic...

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Dades bibliogràfiques
Publicat a:Angew Chem Int Ed Engl
Autors principals: Biagini, Chiara, Fielden, Stephen D. P., Leigh, David A., Schaufelberger, Fredrik, Di Stefano, Stefano, Thomas, Dean
Format: Artigo
Idioma:Inglês
Publicat: John Wiley and Sons Inc. 2019
Matèries:
Communications
Accés en línia:https://ncbi.nlm.nih.gov/pmc/articles/PMC6900173/
https://ncbi.nlm.nih.gov/pubmed/31111628
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201905250
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