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Dissipative Catalysis with a Molecular Machine

We report on catalysis by a fuel‐induced transient state of a synthetic molecular machine. A [2]rotaxane molecular shuttle containing secondary ammonium/amine and thiourea stations is converted between catalytically inactive and active states by pulses of a chemical fuel (trichloroacetic acid), whic...

詳細記述

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書誌詳細
出版年:Angew Chem Int Ed Engl
主要な著者: Biagini, Chiara, Fielden, Stephen D. P., Leigh, David A., Schaufelberger, Fredrik, Di Stefano, Stefano, Thomas, Dean
フォーマット: Artigo
言語:Inglês
出版事項: John Wiley and Sons Inc. 2019
主題:
オンライン・アクセス:https://ncbi.nlm.nih.gov/pmc/articles/PMC6900173/
https://ncbi.nlm.nih.gov/pubmed/31111628
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201905250
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