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A Highly Warped Heptagon‐Containing sp(2) Carbon Scaffold via Vinylnaphthyl π‐Extension

A new strategy is demonstrated for the synthesis of warped, negatively curved, all‐sp(2)‐carbon π‐scaffolds. Multifold C−C coupling reactions are used to transform a polyaromatic borinic acid into a saddle‐shaped polyaromatic hydrocarbon (2) bearing two heptagonal rings. Notably, this Schwarzite sub...

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Detaylı Bibliyografya
Yayımlandı:Angew Chem Int Ed Engl
Asıl Yazarlar: Farrell, Jeffrey M., Grande, Vincenzo, Schmidt, David, Würthner, Frank
Materyal Türü: Artigo
Dil:Inglês
Baskı/Yayın Bilgisi: John Wiley and Sons Inc. 2019
Konular:
Online Erişim:https://ncbi.nlm.nih.gov/pmc/articles/PMC6900032/
https://ncbi.nlm.nih.gov/pubmed/31507020
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201909975
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