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Hydrogen Bonding Between Ions of Like Charge in Ionic Liquids Characterized by NMR Deuteron Quadrupole Coupling Constants—Comparison with Salt Bridges and Molecular Systems

We present deuteron quadrupole coupling constants (DQCC) for hydroxyl‐functionalized ionic liquids (ILs) in the crystalline or glassy states characterizing two types of hydrogen bonding: The regular Coulomb‐enhanced hydrogen bonds between cation and anion (c–a), and the unusual hydrogen bonds betwee...

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Pubblicato in:Angew Chem Int Ed Engl
Autori principali: Khudozhitkov, Alexander E., Neumann, Jan, Niemann, Thomas, Zaitsau, Dzmitry, Stange, Peter, Paschek, Dietmar, Stepanov, Alexander G., Kolokolov, Daniil I., Ludwig, Ralf
Natura: Artigo
Lingua:Inglês
Pubblicazione: John Wiley and Sons Inc. 2019
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Accesso online:https://ncbi.nlm.nih.gov/pmc/articles/PMC6899581/
https://ncbi.nlm.nih.gov/pubmed/31588622
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201912476
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