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Spectroscopic Evidence for Clusters of Like‐Charged Ions in Ionic Liquids Stabilized by Cooperative Hydrogen Bonding

Direct spectroscopic evidence for hydrogen‐bonded clusters of like‐charged ions is reported for ionic liquids. The measured infrared O−H vibrational bands of the hydroxyethyl groups in the cations can be assigned to the dispersion‐corrected DFT calculated frequencies of linear and cyclic clusters. C...

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Bibliografiske detaljer
Udgivet i:Chemphyschem
Main Authors: Knorr, Anne, Stange, Peter, Fumino, Koichi, Weinhold, Frank, Ludwig, Ralf
Format: Artigo
Sprog:Inglês
Udgivet: John Wiley and Sons Inc. 2016
Fag:
Online adgang:https://ncbi.nlm.nih.gov/pmc/articles/PMC4819523/
https://ncbi.nlm.nih.gov/pubmed/26670942
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/cphc.201501134
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