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Rh-Catalyzed Highly Enantioselective Synthesis of Aliphatic Sulfonyl Fluorides

Rh-catalyzed, highly enantioselective (up to 99.8% ee) synthesis of aliphatic sulfonyl fluorides was accomplished. This protocol provides a portal to a class of novel 2-aryl substituted chiral sulfonyl fluorides, which are otherwise extremely difficult to access. This asymmetric synthesis has the fe...

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Vydáno v:iScience
Hlavní autoři: Moku, Balakrishna, Fang, Wan-Yin, Leng, Jing, Li, Linxian, Zha, Gao-Feng, Rakesh, K.P., Qin, Hua-Li
Médium: Artigo
Jazyk:Inglês
Vydáno: Elsevier 2019
Témata:
On-line přístup:https://ncbi.nlm.nih.gov/pmc/articles/PMC6889689/
https://ncbi.nlm.nih.gov/pubmed/31733515
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1016/j.isci.2019.10.051
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