Probing the Hydrogenation of Vinyl Sulfoxides Using para-Hydrogen

[Image: see text] Vinyl sulfoxides are an important functional group used in a wide range of organic transformations. Here, we use [IrCl(COD)(IMes)] where IMes = 1,3-bis(2,4,6-trimethyl-phenyl)imidazole-2-ylidene and COD = cis,cis-1,5-cyclooctadiene to rapidly hydrogenate phenylvinylsulfoxide. We us...

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Bibliografiske detaljer
Udgivet i:Organometallics
Main Authors: Tickner, Ben J., Parker, Rachel R., Whitwood, Adrian C., Duckett, Simon B.
Format: Artigo
Sprog:Inglês
Udgivet: American Chemical Society 2019
Online adgang:https://ncbi.nlm.nih.gov/pmc/articles/PMC6880776/
https://ncbi.nlm.nih.gov/pubmed/31787798
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.organomet.9b00610
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