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1-Aminopyridinium Ylides as Monodentate Directing Groups for sp(3) C—H Bond Functionalization

1-Aminopyridinium ylides are efficient directing groups for palladium-catalyzed β-arylation and alkylation of sp(3) C–H bonds in carboxylic acid derivatives. The efficiency of these directing groups depends on the substitution at the pyridine moiety. The unsubstituted pyridine-derived ylides allow f...

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Detalhes bibliográficos
Publicado no:J Am Chem Soc
Main Authors: Le, Ky Khac Anh, Nguyen, Hanh, Daugulis, Olafs
Formato: Artigo
Idioma:Inglês
Publicado em: 2019
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC6880753/
https://ncbi.nlm.nih.gov/pubmed/31529954
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.9b06643
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