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The frequency-domain infrared spectrum of ammonia encodes changes in molecular dynamics caused by a DC electric field
Ammonia is special. It is nonplanar, yet in v = 1 of the umbrella mode (ν(2)) its inversion motion is faster than J = 0↔1 rotation. Does the simplicity of the Chemist's concept of an electric dipole moment survive the competition between rotation, inversion, and a strong external electric field...
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| Yayımlandı: | Proc Natl Acad Sci U S A |
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| Asıl Yazarlar: | , , , |
| Materyal Türü: | Artigo |
| Dil: | Inglês |
| Baskı/Yayın Bilgisi: |
National Academy of Sciences
2019
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| Konular: | |
| Online Erişim: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6876197/ https://ncbi.nlm.nih.gov/pubmed/31690662 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1073/pnas.1914432116 |
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