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The frequency-domain infrared spectrum of ammonia encodes changes in molecular dynamics caused by a DC electric field
Ammonia is special. It is nonplanar, yet in v = 1 of the umbrella mode (ν(2)) its inversion motion is faster than J = 0↔1 rotation. Does the simplicity of the Chemist's concept of an electric dipole moment survive the competition between rotation, inversion, and a strong external electric field...
Zapisane w:
| Wydane w: | Proc Natl Acad Sci U S A |
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| Główni autorzy: | , , , |
| Format: | Artigo |
| Język: | Inglês |
| Wydane: |
National Academy of Sciences
2019
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| Hasła przedmiotowe: | |
| Dostęp online: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6876197/ https://ncbi.nlm.nih.gov/pubmed/31690662 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1073/pnas.1914432116 |
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