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Scope and Limitations of γ-Valerolactone (GVL) as a Green Solvent to be Used with Base for Fmoc Removal in Solid Phase Peptide Synthesis

GVL is a green solvent used in Fmoc-based solid-phase peptide synthesis. It is susceptible to ring opening in the presence of bases such as piperidines, which are used to remove the Fmoc protecting group. Here we studied the formation of the corresponding acyl piperidides by time-dependent monitorin...

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Publicado en:Molecules
Main Authors: Kumar, Ashish, Sharma, Anamika, de la Torre, Beatriz G., Albericio, Fernando
Formato: Artigo
Idioma:Inglês
Publicado: MDPI 2019
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Acceso en liña:https://ncbi.nlm.nih.gov/pmc/articles/PMC6864637/
https://ncbi.nlm.nih.gov/pubmed/31694279
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3390/molecules24214004
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