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Diazotization of S-Sulfonyl-cysteines
[Image: see text] We report the preparation of enantiomerically enriched β-thio-α-hydroxy and α-chloro carboxylic acid and ester building blocks by diazotization of S-sulfonyl-cysteines. The thiosulfonate protecting group demonstrated resistance to oxidation and attenuation of sulfur’s nucleophilici...
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| Publicado no: | J Org Chem |
|---|---|
| Main Authors: | , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
American Chemical
Society
2019
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| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6862327/ https://ncbi.nlm.nih.gov/pubmed/31657562 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.joc.9b02630 |
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