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Planar three-coordinate iron sulfide in a synthetic [4Fe-3S] cluster with biomimetic reactivity
Iron-sulfur clusters are emerging as reactive sites for the reduction of small-molecule substrates. However, the four-coordinate iron sites of typical iron-sulfur clusters rarely react with substrates, implicating three-coordinate iron. This idea is untested because fully sulfide-coordinated three-c...
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| Publicado en: | Nat Chem |
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| Main Authors: | , , , , , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado: |
2019
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| Assuntos: | |
| Acceso en liña: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6858550/ https://ncbi.nlm.nih.gov/pubmed/31611632 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1038/s41557-019-0341-7 |
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