Probing the Structural Evolution of the Hydrated Electron in Water Cluster Anions (H(2)O)(n)(–), n ≤ 200, by Electronic Absorption Spectroscopy

[Image: see text] Electronic absorption spectra of water cluster anions (H(2)O)(n)(–), n ≤ 200, at T = 80 K are obtained by photodissociation spectroscopy and compared with simulations from literature and experimental data for bulk hydrated electrons. Two almost isoenergetic electron binding motifs...

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Publicado en:J Am Chem Soc
Autores principales: Herburger, Andreas, Barwa, Erik, Ončák, Milan, Heller, Jakob, van der Linde, Christian, Neumark, Daniel M., Beyer, Martin K.
Formato: Artigo
Lenguaje:Inglês
Publicado: American Chemical Society 2019
Acceso en línea:https://ncbi.nlm.nih.gov/pmc/articles/PMC6856957/
https://ncbi.nlm.nih.gov/pubmed/31651160
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.9b10347
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