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Steric and electronic control of an ultrafast isomerization

Synthetic control of the influence of steric and electronic factors on the ultrafast (picosecond) isomerization of penta-coordinate ruthenium dithietene complexes (Ru((CF(3))(2)C(2)S(2))(CO)(L)(2), where L = a monodentate phosphine ligand) is reported. Seven new ruthenium dithietene complexes were p...

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Détails bibliographiques
Publié dans:Chem Sci
Auteurs principaux: Porter, Tyler M., Ostericher, Andrew L., Kubiak, Clifford P.
Format: Artigo
Langue:Inglês
Publié: Royal Society of Chemistry 2019
Sujets:
Accès en ligne:https://ncbi.nlm.nih.gov/pmc/articles/PMC6836746/
https://ncbi.nlm.nih.gov/pubmed/31853348
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c9sc02359c
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