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Direct observation of the intermediate in an ultrafast isomerization

Using a combination of two-dimensional infrared (2D IR) and variable temperature Fourier transform infrared (FTIR) spectroscopies the rapid structural isomerization of a five-coordinate ruthenium complex is investigated. In methylene chloride, three exchanging isomers were observed: (1) square pyram...

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Detalhes bibliográficos
Publicado no:Chem Sci
Main Authors: Porter, Tyler M., Wang, Jiaxi, Li, Yingmin, Xiang, Bo, Salsman, Catherine, Miller, Joel S., Xiong, Wei, Kubiak, Clifford P.
Formato: Artigo
Idioma:Inglês
Publicado em: Royal Society of Chemistry 2018
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC6333165/
https://ncbi.nlm.nih.gov/pubmed/30713623
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c8sc03258k
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