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Nickel-catalyzed intermolecular oxidative Heck arylation driven by transfer hydrogenation

The conventional oxidative Heck reaction between aryl boronic acids and alkenes typically involved the Pd(II)/Pd(0)/Pd(II) catalytic cycle incorporating an external oxidant and often suffered C=C bond isomerization for internal alkyl-substituted alkenes via chain-walking. Herein, we demonstrate that...

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Detalhes bibliográficos
Publicado no:Nat Commun
Main Authors: Lv, Honggui, Kang, Huiying, Zhou, Biying, Xue, Xiaosong, Engle, Keary M., Zhao, Dongbing
Formato: Artigo
Idioma:Inglês
Publicado em: Nature Publishing Group UK 2019
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC6831602/
https://ncbi.nlm.nih.gov/pubmed/31690717
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1038/s41467-019-12949-1
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