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Reductive Arylation of Amides via a Nickel-Catalyzed Suzuki–Miyaura Coupling and Transfer Hydrogenation Cascade

We report a means to achieve the addition of two disparate nucleophiles to the amide carbonyl carbon in a single operational step. Our method takes advantage of non-precious metal catalysis and allows for the facile conversion of amides to chiral alcohols via a one-pot Suzuki–Miyaura cross-coupling...

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Detalhes bibliográficos
Publicado no:Angew Chem Int Ed Engl
Main Authors: Boit, Timothy B., Mehta, Milauni M., Kim, Junyong, Baker, Emma L., Garg, Neil K.
Formato: Artigo
Idioma:Inglês
Publicado em: 2020
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC7855255/
https://ncbi.nlm.nih.gov/pubmed/33029868
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.202012048
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