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Chemoselective Benzylation of Aldehydes Using Lewis Base Activated Boronate Nucleophiles
A benzylation of aldehydes using primary and secondary benzylboronic acid pinacol esters is reported. Activation of the boronic ester with s-butyllithium rendered it nucleophilic toward aldehydes. The activated nucleophile chemoselectively transfers the benzyl group over the s-butyl group, providing...
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| Publicado no: | Organometallics |
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| Main Authors: | , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2018
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6824429/ https://ncbi.nlm.nih.gov/pubmed/31680714 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.organomet.8b00085 |
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