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Catalyst-Controlled 1,2- and 1,1-Arylboration of α-Alkyl Alkenyl Arenes
Two methods are reported for the 1,2- and 1,1-arylboration of α-methyl vinyl arenes. In the case of 1,2-arylboration, the formation of a quaternary center occurred through a rare cross-coupling reaction of a tertiary organometallic complex. 1,1-Arylboration was enabled by catalyst optimization and o...
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| Publicado no: | Angew Chem Int Ed Engl |
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| Main Authors: | , , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2019
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6823597/ https://ncbi.nlm.nih.gov/pubmed/30521697 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201812533 |
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