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Catalyst-Controlled 1,2- and 1,1-Arylboration of α-Alkyl Alkenyl Arenes

Two methods are reported for the 1,2- and 1,1-arylboration of α-methyl vinyl arenes. In the case of 1,2-arylboration, the formation of a quaternary center occurred through a rare cross-coupling reaction of a tertiary organometallic complex. 1,1-Arylboration was enabled by catalyst optimization and o...

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Publicat a:Angew Chem Int Ed Engl
Autors principals: Bergmann, Allison M., Dorn, Stanna K., Smith, Kevin B., Logan, Kaitlyn M., Brown, M. Kevin
Format: Artigo
Idioma:Inglês
Publicat: 2019
Matèries:
Accés en línia:https://ncbi.nlm.nih.gov/pmc/articles/PMC6823597/
https://ncbi.nlm.nih.gov/pubmed/30521697
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201812533
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