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Syntheses of Molybdenum Adamantylimido and t-Butylimido Alkylidene Chloride Complexes Using HCI and Diphenylmethylphosphine

Reactions between Mo(N-t-Bu)(2)(CH(2)-t-Bu)(2) or Mo(NAdamantyl)(2)(CH(2)CMe(2)Ph)(2) and 3 equiv of HCl in the presence of 1 equiv of PPh(2)Me yield Mo(NR)(CHR’)(PPh(2)Me)Cl(2) complexes, from which Mo(NR)(CHR’)(PPh(2)Me)(OAr)Cl complexes (OAr = a 2,6-terphenoxide) can be prepared. The Mo(NR)(CHR’)...

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Bibliografiske detaljer
Udgivet i:Organometallics
Main Authors: Bukhryakov, Konstantin V., VenkatRamani, Sudarsan, Tsay, Charlene, Hoveyda, Amir, Schrock, Richard R.
Format: Artigo
Sprog:Inglês
Udgivet: 2017
Fag:
Online adgang:https://ncbi.nlm.nih.gov/pmc/articles/PMC6816759/
https://ncbi.nlm.nih.gov/pubmed/31659999
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.organomet.7b00647
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