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Syntheses of Molybdenum Oxo Alkylidene Complexes Through Addition of Water to an Alkylidyne Complex
Addition of one equiv of water to Mo(CAr)[OCMe(CF(3))(2)](3)(1,2-dimethoxyethane) (2, Ar = o-(OMe)C(6)H(4)) in the presence of PPhMe(2) leads to formation of Mo(O)(CHAr)[OCMe(CF(3))(2)](2)(PPhMe(2)) (3(PPhMe(2))) in 34% yield. Addition of one equiv of water alone to 2 produces the dimeric alkylidyne...
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| 出版年: | J Am Chem Soc |
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| 主要な著者: | , , , , |
| フォーマット: | Artigo |
| 言語: | Inglês |
| 出版事項: |
2018
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| 主題: | |
| オンライン･アクセス: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6293189/ https://ncbi.nlm.nih.gov/pubmed/29432003 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.8b00499 |
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