Preliminary Assignment of Protonated and Deprotonated Homocitrates in Extracted FeMo-cofactors by Comparisons with Molybdenum(IV) Lactates and Oxidovanadium Glycolates

A similar pair of protonated and deprotonated mononuclear oxidovanadium glycolates [VO(Hglyc)(phen)(H(2)O)]Cl·2H(2)O (1) and [VO(glyc)(bpy)(H(2)O)] (2) and a mixed-(de)protonated oxidovanadium triglycolate (NH(4))(2)[VO(Hglyc)(2)(glyc)]·H(2)O (3) were isolated and examined. The ≡C–O(H) (≡C–OH or ≡C–...

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Veröffentlicht in:Inorg Chem
Hauptverfasser: Jin, Wan-Ting, Wang, Hongxin, Wang, Si-Yuan, Dapper, Christie H., Li, Xing, Newton, William E., Zhou, Zhao-Hui, Cramer, Stephen P.
Format: Artigo
Sprache:Inglês
Veröffentlicht: 2019
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Article
Online Zugang:https://ncbi.nlm.nih.gov/pmc/articles/PMC6813765/
https://ncbi.nlm.nih.gov/pubmed/30726074
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.inorgchem.8b03108
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