Iodine Adsorption in a Redox-Active Metal–Organic Framework: Electrical Conductivity Induced by Host−Guest Charge-Transfer

[Image: see text] We report a comparative study of the binding of I(2) (iodine) in a pair of redox-active metal–organic framework (MOF) materials, MFM-300(V(III)) and its oxidized, deprotonated analogue, MFM-300(V(IV)). Adsorption of I(2) in MFM-300(V(III)) triggers a host-to-guest charge-transfer,...

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Publié dans:Inorg Chem
Auteurs principaux: Zhang, Xinran, da Silva, Ivan, Fazzi, Rodrigo, Sheveleva, Alena M., Han, Xue, Spencer, Ben F., Sapchenko, Sergey A., Tuna, Floriana, McInnes, Eric J. L., Li, Ming, Yang, Sihai, Schröder, Martin
Format: Artigo
Langue:Inglês
Publié: American Chemical Society 2019
Accès en ligne:https://ncbi.nlm.nih.gov/pmc/articles/PMC6806328/
https://ncbi.nlm.nih.gov/pubmed/31566954
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.inorgchem.9b02176
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