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Iodine Adsorption in a Redox-Active Metal–Organic Framework: Electrical Conductivity Induced by Host−Guest Charge-Transfer
[Image: see text] We report a comparative study of the binding of I(2) (iodine) in a pair of redox-active metal–organic framework (MOF) materials, MFM-300(V(III)) and its oxidized, deprotonated analogue, MFM-300(V(IV)). Adsorption of I(2) in MFM-300(V(III)) triggers a host-to-guest charge-transfer,...
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| Publicado no: | Inorg Chem |
|---|---|
| Main Authors: | , , , , , , , , , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
American
Chemical Society
2019
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| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6806328/ https://ncbi.nlm.nih.gov/pubmed/31566954 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.inorgchem.9b02176 |
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