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Site-selective remote C(sp(3))–H heteroarylation of amides via organic photoredox catalysis

Radical translocation processes triggered by nitrogen-centered radicals (NCRs), such as 1,5-hydrogen atom transfers (1,5-HAT), demonstrated by the well-established Hofmann-Löffler-Freytag (HLF) reaction, provide an attractive approach for the controllable and selective functionalization of remote in...

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Publicado en:Nat Commun
Main Authors: Chen, Hui, Fan, Wenjing, Yuan, Xiang-Ai, Yu, Shouyun
Formato: Artigo
Idioma:Inglês
Publicado: Nature Publishing Group UK 2019
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Acceso en liña:https://ncbi.nlm.nih.gov/pmc/articles/PMC6800443/
https://ncbi.nlm.nih.gov/pubmed/31628325
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1038/s41467-019-12722-4
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