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Photoredox-mediated remote C(sp(3))–H heteroarylation of free alcohols
We report an efficient and economical method for remote δ C(sp(3))–H heteroarylation of free aliphatic alcohols using a hypervalent iodine PFBI-OH oxidant under photoredox catalysis. The reaction sequence involves in situ alcoholysis of PFBI-OH with alcohol, generation of an alkoxy radical intermedi...
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| Publicat a: | Chem Sci |
|---|---|
| Autors principals: | , , , |
| Format: | Artigo |
| Idioma: | Inglês |
| Publicat: |
Royal Society of Chemistry
2018
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| Matèries: | |
| Accés en línia: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6345347/ https://ncbi.nlm.nih.gov/pubmed/30774869 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c8sc04134b |
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