Probing ultrafast C–Br bond fission in the UV photochemistry of bromoform with core-to-valence transient absorption spectroscopy

UV pump–extreme UV (XUV) probe femtosecond transient absorption spectroscopy is used to study the 268 nm induced photodissociation dynamics of bromoform (CHBr(3)). Core-to-valence transitions at the Br(3d) absorption edge (∼70 eV) provide an atomic scale perspective of the reaction, sensitive to cha...

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Publicat a:Struct Dyn
Autors principals: Toulson, Benjamin W., Borgwardt, Mario, Wang, Han, Lackner, Florian, Chatterley, Adam S., Pemmaraju, C. D., Neumark, Daniel M., Leone, Stephen R., Prendergast, David, Gessner, Oliver
Format: Artigo
Idioma:Inglês
Publicat: American Crystallographic Association 2019
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ARTICLES
Accés en línia:https://ncbi.nlm.nih.gov/pmc/articles/PMC6800284/
https://ncbi.nlm.nih.gov/pubmed/31649963
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1063/1.5113798
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