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Excited-state proton transfer relieves antiaromaticity in molecules
Baird’s rule explains why and when excited-state proton transfer (ESPT) reactions happen in organic compounds. Bifunctional compounds that are [4n + 2] π-aromatic in the ground state, become [4n + 2] π-antiaromatic in the first (1)ππ* states, and proton transfer (either inter- or intramolecularly) h...
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| Publicado no: | Proc Natl Acad Sci U S A |
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| Main Authors: | , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
National Academy of Sciences
2019
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6789556/ https://ncbi.nlm.nih.gov/pubmed/31554699 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1073/pnas.1908516116 |
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