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Ketones and aldehydes as alkyl radical equivalents for C─H functionalization of heteroarenes

The polar nature of the C═O bond commonly allows it to undergo direct attack by nucleophiles at the electrophilic carbon atom in which ketones and aldehydes act as alkyl carbocation equivalents. In contrast, transformations in which ketones and aldehydes act as alkyl radical equivalents (generated i...

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Bibliografische gegevens
Gepubliceerd in:Sci Adv
Hoofdauteurs: Dong, Jianyang, Wang, Zhen, Wang, Xiaochen, Song, Hongjian, Liu, Yuxiu, Wang, Qingmin
Formaat: Artigo
Taal:Inglês
Gepubliceerd in: American Association for the Advancement of Science 2019
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Online toegang:https://ncbi.nlm.nih.gov/pmc/articles/PMC6788867/
https://ncbi.nlm.nih.gov/pubmed/31646180
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1126/sciadv.aax9955
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