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Ketones and aldehydes as alkyl radical equivalents for C─H functionalization of heteroarenes
The polar nature of the C═O bond commonly allows it to undergo direct attack by nucleophiles at the electrophilic carbon atom in which ketones and aldehydes act as alkyl carbocation equivalents. In contrast, transformations in which ketones and aldehydes act as alkyl radical equivalents (generated i...
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| Publicado no: | Sci Adv |
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| Main Authors: | , , , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
American Association for the Advancement of Science
2019
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6788867/ https://ncbi.nlm.nih.gov/pubmed/31646180 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1126/sciadv.aax9955 |
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