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Spectroscopic X-ray and Mössbauer Characterization of M(6) and M(5) Iron(Molybdenum)-Carbonyl Carbide Clusters: High Carbide-Iron Covalency Enhances Local Iron Site Electron Density Despite Cluster Oxidation
[Image: see text] The present study employs a suite of spectroscopic techniques to evaluate the electronic and bonding characteristics of the interstitial carbide in a set of iron-carbonyl-carbide clusters, one of which is substituted with a molybdenum atom. The M(6)C and M(5)C clusters are the dian...
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| Publicado no: | Inorg Chem |
|---|---|
| Main Authors: | , , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
American
Chemical Society
2019
|
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6784818/ https://ncbi.nlm.nih.gov/pubmed/31553598 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.inorgchem.9b01870 |
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