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Mechanistic Insight into the Ring-Opening Polymerization of ε-Caprolactone and L-Lactide Using Ketiminate-Ligated Aluminum Catalysts

The reactivity and the reaction conditions of the ring-opening polymerization of ε-caprolactone (ε-CL) and L-lactide (LA) initiated by aluminum ketiminate complexes have been shown differently. Herein, we account for the observation by studying the mechanisms on the basis of density functional theor...

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Detalhes bibliográficos
Publicado no:Polymers (Basel)
Main Authors: Lin, Ya-Fan, Jheng, Nai-Yuan
Formato: Artigo
Idioma:Inglês
Publicado em: MDPI 2019
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC6780811/
https://ncbi.nlm.nih.gov/pubmed/31546919
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3390/polym11091530
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