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Regulating the Basicity of Metal–Oxido Complexes with a Single Hydrogen Bond and its Effect on C–H Bond Cleavage
The functionalization of C–H bonds is an essential reaction in biology and chemistry. Metalloenzymes that often exhibit this type of reactivity contain metal-oxido intermediates which are directly involved the initial cleavage of the C–H bonds. Regulation of the cleavage process is achieved, in part...
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| Pubblicato in: | J Am Chem Soc |
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| Autori principali: | , , , , , |
| Natura: | Artigo |
| Lingua: | Inglês |
| Pubblicazione: |
2019
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| Soggetti: | |
| Accesso online: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6776423/ https://ncbi.nlm.nih.gov/pubmed/31274298 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.9b03688 |
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