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Hemilabile Benzyl Ether Enables γ-C(sp(3))–H Carbonylation and Olefination of Alcohols
Pd-catalyzed C(sp(3))–H activation of alcohol typically shows β-selectivity due to the required distance between the chelating atom in the attached directing group and the targeted C–H bonds. Herein we report the design of hemilabile directing group, which exploit the chelation of a readily removabl...
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| Publicado no: | J Am Chem Soc |
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| Main Authors: | , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2019
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6776245/ https://ncbi.nlm.nih.gov/pubmed/31519108 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.9b08238 |
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