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Transition state analysis of an enantioselective Michael addition by a bifunctional thiourea organocatalyst
The mechanism of the enantioselective Michael addition of diethyl malonate to trans-β-nitrostyrene catalyzed by a tertiary amine thiourea organocatalyst is explored using experimental (13)C kinetic isotope effects and density functional theory calculations. Large primary (13)C KIEs on the bond-formi...
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| Publié dans: | Org Biomol Chem |
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| Auteurs principaux: | , , , |
| Format: | Artigo |
| Langue: | Inglês |
| Publié: |
2019
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| Sujets: | |
| Accès en ligne: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6774437/ https://ncbi.nlm.nih.gov/pubmed/30942247 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c9ob00072k |
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